ELECTROCHEMILUMINESCENCE OF OSMIUM COMPLEXES - SPECTRAL, ELECTROCHEMICAL, AND MECHANISTIC STUDIES

被引：40

作者：

ABRUNA, HD

机构：

[1] Cornell Univ, Dep of Chemistry,, Ithaca, NY, USA, Cornell Univ, Dep of Chemistry, Ithaca, NY, USA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1985年 / 132卷 / 04期

关键词：

CHEMICAL REACTIONS - Reaction Kinetics - CHEMILUMINESCENCE - ELECTROCHEMISTRY - LUMINESCENCE;

D O I：

10.1149/1.2113970

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

This study presents further electrochemical and electrochemiluminescent characterization of phenanthroline and bipyridine complexes of osmium. It is found that a large number of these complexes will give rise to ECL emission, although, in some cases, the observed ECL intensity was much lower than had been anticipated. It is also demonstrated that surface ECL can also be observed from the films of electropolymerized complexes. Though the emission arising from these films is not as intense as that observed from electropolymerized Ru(vinyl-bipyridine)//3**2** plus films, it is much longer lived.

引用

页码：842 / 849

页数：8

共 24 条

[1] ELECTROGENERATED CHEMI-LUMINESCENCE .40. A CHEMI-LUMINESCENT POLYMER BASED ON THE TRIS(4-VINYL-4'-METHYL-2,2'-BIPYRIDYL)RUTHENIUM(II) SYSTEM [J].