TIME-RESOLVED INFRARED-SPECTROSCOPY OF EXCITED-STATES OF TRANSITION-METAL SPECIES

被引：71
作者：
TURNER, JJ
GEORGE, MW
JOHNSON, FPA
WESTWELL, JR
机构：
[1] Department of Chemistry, University of Nottingham, Nottingham
来源：
COORDINATION CHEMISTRY REVIEWS | 1993年 / 125卷 / 1-2期
关键词：
D O I：
10.1016/0010-8545(93)85011-R
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This article describes examples of the application of time-resolved infrared spectroscopy (TRIR) to the probing of the excited states of transition metal species. Other ''direct'' methods for excited states include time-resolved absorption spectroscopy, and, more importantly, time-resolved resonance Raman spectroscopy (TR3). Both of these techniques have limitations and hence TRIR is of value in complementing them. The common 'indirect'' methods are absorption, emission, and excitation spectroscopies, to which has been more recently added, resonance Raman, particularly in the time-dependent formulation. The relevance of these methods is also discussed.
引用
收藏
页码：101 / 114
页数：14
相关论文
共 57 条
[1]   A Relation Between Internuclear Distances and Bond Force Constants [J].
Badger, Richard M. .
JOURNAL OF CHEMICAL PHYSICS, 1934, 2 (03)
[2]   The relation between internuclear distances and the force constants of diatomic molecules [J].
Badger, RM .
PHYSICAL REVIEW, 1935, 48 (03) :284-285
[3]  
Balzani V., 1970, PHOTOCHEMISTRY COORD
[4]  
BALZANI V, 1991, SUPRAMOLECULAR PHOTO
[5]   OLIGOMERIC DICYANOBIS(POLYPYRIDINE)RUTHENIUM(II) COMPLEXES - SYNTHESIS AND SPECTROSCOPIC AND PHOTOPHYSICAL PROPERTIES [J].
BIGNOZZI, CA ;
ROFFIA, S ;
CHIORBOLI, C ;
DAVILA, J ;
INDELLI, MT ;
SCANDOLA, F .
INORGANIC CHEMISTRY, 1989, 28 (24) :4350-4358
[6]   ELECTRONIC COUPLING IN CYANO-BRIDGED RUTHENIUM POLYPYRIDINE COMPLEXES AND ROLE OF ELECTRONIC EFFECTS ON CYANIDE STRETCHING FREQUENCIES [J].
BIGNOZZI, CA ;
ARGAZZI, R ;
SCHOONOVER, JR ;
GORDON, KC ;
DYER, RB ;
SCANDOLA, F .
INORGANIC CHEMISTRY, 1992, 31 (25) :5260-5267
[7]   VIBRATIONAL SPECTROSCOPY OF THE ELECTRONICALLY EXCITED-STATE .5. TIME-RESOLVED RESONANCE RAMAN-STUDY OF TRIS(BIPYRIDINE)RUTHENIUM(II) AND RELATED COMPLEXES - DEFINITIVE EVIDENCE FOR THE LOCALIZED MLCT STATE [J].
BRADLEY, PG ;
KRESS, N ;
HORNBERGER, BA ;
DALLINGER, RF ;
WOODRUFF, WH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (25) :7441-7446
[8]   PHOTOLYSIS AND SPECTROSCOPY WITH POLARIZED-LIGHT - KEY TO PHOTOCHEMISTRY OF CR(CO)5 AND RELATED SPECIES [J].
BURDETT, JK ;
GRZYBOWSKI, JM ;
PERUTZ, RN ;
POLIAKOFF, M ;
TURNER, JJ ;
TURNER, RF .
INORGANIC CHEMISTRY, 1978, 17 (01) :147-154
[9]   RESONANCE RAMAN-SPECTROSCOPY, AND ITS APPLICATION TO INORGANIC-CHEMISTRY [J].
CLARK, RJH ;
DINES, TJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (02) :131-158
[10]   X-RAY ABSORPTION STUDY OF OCTAFLUORODIRHENATE(III) - EXAFS STRUCTURES AND RESONANCE RAMAN-SPECTROSCOPY OF OCTAHALODIRHENATES [J].
CONRADSON, SD ;
SATTELBERGER, AP ;
WOODRUFF, WH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (04) :1309-1311
123456