INFRARED SPECTROELECTROCHEMICAL OBSERVATION OF THE REDUCTION OF IRON PENTACARBONYL

被引:15
作者
CURRAN, DJ [1 ]
GRAHAM, PB [1 ]
RAUSCH, MD [1 ]
机构
[1] UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01003
关键词
D O I
10.1021/om00030a058
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The electrochemical reduction of iron pentacarbonyl was studied using infrared spectra collected simultaneously with the electrochemical conversion. Evidence for a mechanism proceeding through the iron tetracarbonyl dianion is observed.
引用
收藏
页码:2380 / 2382
页数:3
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