CRYSTAL-STRUCTURE OF CIS-(CARBON MONOXIDE)(ETA-1-CARBON DIOXIDE)BIS(2,2'-BIPYRIDYL)RUTHENIUM, AN ACTIVE SPECIES IN CATALYTIC CO2 REDUCTION AFFORDING CO AND HCOO-

被引：74

作者：

TANAKA, H ^{[1
]}

NAGAO, H ^{[1
]}

PENG, SM ^{[1
]}

TANAKA, K ^{[1
]}

机构：

[1] GRAD UNIV ADV STUDIES,INST MOLEC SCI,DEPT STRUCT MOLEC SCI,MYODAIJI,OKAZAKI 444,JAPAN

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 04期

关键词：

D O I：

10.1021/om00040a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A reaction of [Ru(bpy)2(CO)2](PF6)2 with 2 equiv of Bu4NOH in H2O/EtOH (1:1 v/v) affords an eta(1)-CO2 complex, [Ru(bpy)2(CO)(COO)].3H2O. An addition of an aqueous HCl solution to a MeOH solution of [Ru(bpy)2-(CO)(COO)].3H2O quantitatively regenerates [Ru(bpy)2-(CO)2]2+.

引用

页码：1450 / 1451

页数：2

共 20 条

[1] COBALT(II) TETRAPHENYLPORPHYRIN PYRIDINE COMPLEX FIXED ON A GLASSY-CARBON ELECTRODE AND ITS PROMINENT CATALYTIC ACTIVITY FOR REDUCTION OF CARBON-DIOXIDE
ATOGUCHI, T
ARAMATA, A
KAZUSAKA, A
ENYO, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (03) : 156 - 157
[2] CARBON-DIOXIDE COORDINATION CHEMISTRY .5. THE PREPARATION AND STRUCTURE OF RH(ETA-1-CO2)(CL)(DIARS)2
CALABRESE, JC
HERSKOVITZ, T
KINNEY, JB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) : 5914 - 5915
[3] THE IRIDIUM COMPLEX CATALYZED REDUCTION OF CARBON-DIOXIDE TO METHOXIDE BY ALKYLSILANES
EISENSCHMID, TC
EISENBERG, R
[J]. ORGANOMETALLICS, 1989, 8 (07) : 1822 - 1824
[4] CARBON-DIOXIDE ACTIVATION BY COBALT(I) MACROCYCLES - FACTORS AFFECTING CO2 AND CO BINDING
FUJITA, E
CREUTZ, C
SUTIN, N
SZALDA, DJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 343 - 353
[5] CARBON-DIOXIDE FIXATION - BIFUNCTIONAL COMPLEXES CONTAINING ACIDIC AND BASIC SITES WORKING AS REVERSIBLE CARRIERS
GAMBAROTTA, S
ARENA, F
FLORIANI, C
ZANAZZI, PF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (19) : 5082 - 5092
[6] ELECTROCATALYTIC ACTIVITY OF ELECTROPOLYMERIZED FILMS OF BIS(VINYLTERPYRIDINE)COBALT(2+) FOR THE REDUCTION OF CARBON-DIOXIDE AND OXYGEN
HURRELL, HC
MOGSTAD, AL
USIFER, DA
POTTS, KT
ABRUNA, HD
[J]. INORGANIC CHEMISTRY, 1989, 28 (06) : 1080 - 1084
[7] ELECTROCHEMICAL CO2 REDUCTION CATALYZED BY [RU(BPY)2(CO)2]2+ AND [RU(BPY)2(CO)CL]+ - THE EFFECT OF PH ON THE FORMATION OF CO AND HCOO-
ISHIDA, H
TANAKA, K
TANAKA, T
[J]. ORGANOMETALLICS, 1987, 6 (01) : 181 - 186
[8] LIGAND EFFECTS OF RUTHENIUM 2,2'-BIPYRIDINE AND 1,10-PHENANTHROLINE COMPLEXES ON THE ELECTROCHEMICAL REDUCTION OF CO2
ISHIDA, H
FUJIKI, K
OHBA, T
OHKUBO, K
TANAKA, K
TERADA, T
TANAKA, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (07): : 2155 - 2160
[9] SELECTIVE FORMATION OF HCOO- IN THE ELECTROCHEMICAL CO2 REDUCTION CATALYZED BY [RU(BPY)2(CO)2]2+ (BPY = 2,2'-BIPYRIDINE)
ISHIDA, H
TANAKA, H
TANAKA, K
TANAKA, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (02) : 131 - 132
[10] PHOTOCHEMICAL CO2 REDUCTION CATALYZED BY [RU(BPY)2(CO)2]2+ USING TRIETHANOLAMINE AND 1-BENZYL-1,4-DIHYDRONICOTINAMIDE AS AN ELECTRON-DONOR
ISHIDA, H
TERADA, T
TANAKA, K
TANAKA, T
[J]. INORGANIC CHEMISTRY, 1990, 29 (05) : 905 - 911

← 1 2 →