INCREASE IN THE PSC-FORMATION PROBABILITY CAUSED BY HIGH-FLYING AIRCRAFT

The saturation temperature T(sat) for the formation of polar stratospheric clouds (PSC) strongly depends on the local partial pressures of nitric acid and water vapour, and thus is sensitive to NO(x) and H2O-injection due to exhaust from aircraft in the stratosphere. The present paper investigates this effect, using daily stratospheric temperature data from the northern hemisphere compiled over the last 25 years by the Free University of Berlin. For Type-I PSC the data were examined for temperatures T < T(sat) - 3 K, which would allow for a supercooling of about the 3 K measured in a previous arctic winter balloon mission, in effect corresponding to a large HNO3-supersaturation. We show that this is required to overcome the heterogeneous nucleation energy barrier. We compare the analyses of both a background atmosphere and one perturbed by a fleet of 600 stratospheric aircraft flying at approximately 22 km altitude. The result is that between December and March in the polar cap region there might be more than a doubling in the occurence of Type-I PSCs and an even stronger increase of Type-II PSCs, and accordingly a substantial enhancement in the potential ozone destruction by chlorine radicals.