DOUBLE PHOTOIONIZATION OF CO2, OCS, C2H2, CF4, AND C6H6 STUDIED BY THRESHOLD PHOTOELECTRONS COINCIDENCE (TPESCO) SPECTROSCOPY

被引：90

作者：

HALL, RI

AVALDI, L

DAWBER, G

MCCONKEY, AG

MACDONALD, MA

KING, GC

机构：

[1] CNR,IMAI,AREA RIC ROMA,I-00016 MONTEROTONDO,ITALY

[2] UNIV MANCHESTER,SCHUSTER LAB,DEPT PHYS,MANCHESTER M13 9PL,LANCS,ENGLAND

[3] SERC,DARESBURY LAB,WARRINGTON WA4 4AD,CHESHIRE,ENGLAND

来源：

CHEMICAL PHYSICS | 1994年 / 187卷 / 1-2期

关键词：

D O I：

10.1016/0301-0104(94)00188-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Double photoionization of CO2, OCS, C2H2, CF4 and C6H6 molecules has been studied in an electron-electron coincidence experiments, where nearly zero kinetic energy (less-than-or-equal-to20 meV) electrons are detected. This first application of TPEsCO spectroscopy to polyatomic molecules confirms the ability of this experimental technique to determine accurate double ionization potentials and locate excited electronic states. The spectrum of benzene reveals what appears to be the first observation of vibrational structure in a polyatomic dication.

引用

页码：125 / 135

页数：11

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