FROM PARA-DIMETHOXYBENZENE TOWARD CROWNBENZENOPHANES .2. SYNTHESIS, X-RAY STRUCTURE AND FLUORESCENCE EMISSION PROPERTIES OF 1,3,10,13,16,19,22-HEPTAOXA(3,13)[28]PARACYCLOPHANE AND ITS COMPLEX WITH SODIUM-CATION

被引：10

作者：

MARSAU, P

ANDRIANATOANDRO, H

WILLMS, T

DESVERGNE, JP

BOUASLAURENT, H

HOPF, H

UTERMOHLEN, R

机构：

[1] UNIV BORDEAUX 1,URA 348,F-33405 TALENCE,FRANCE

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ORGAN CHEM,W-3300 BRAUNSCHWEIG,GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 06期

关键词：

SUPRAMOLECULAR CHEMISTRY; CROWN ETHERS; PHANES; FLUID SOLUTIONS AND SINGLE CRYSTALS; SPECTROSCOPIC PROPERTIES OF;

D O I：

10.1002/cber.19931260626

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and X-ray molecular structure of the title compound, an heptaoxa[3,13]paracyclophane, as well as that of its 1:1 sodium complex are described; a study of the absorption and fluorescence spectra indicates that this crown-cyclophane behaves as a hybrid between strained classical cyclophanes and large macrocycles.

引用

页码：1441 / 1446

页数：6

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