SYNTHESIS AND STRUCTURE OF A STABLE SELENODIIMIDE COMPLEX

被引：21
作者：
GINDL, J
BJORGVINSSON, M
ROESKY, HW
FREIREERDBRUGGER, C
SHELDRICK, GM
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 05期
关键词：
D O I：
10.1039/dt9930000811
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The stable selenodiimide complex SnCl4[(ButN=)2Se] 1 has been prepared from Se[NBut(SiMe3)]2 and SnCl4, and also by treating the unstable (ButN=)2Se (obtained from NButH2 and SeCl4) with SnCl4; the crystal structure of 1.2thf indicates appreciable Se=N double-bond character [171.0(3) pm] but also shows that the selenium atom is unexpectedly co-ordinated by the two tetrahydrofuran (thf) oxygens.
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页码：811 / 812
页数：2
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