SYNTHESES AND X-RAY CRYSTAL-STRUCTURES OF [BIS)(3,5-DIMETHYLPYRAZOLYL)3HYDRIDOBORATO(IN]I AND [BIS)(PYRAZOLYL)3METHYLGALLATO(IN][INI4]

被引：24

作者：

FRAZER, A

PIGGOTT, B ^{[1
]}

HARMAN, M

MAZID, M

HURSTHOUSE, MB

机构：

[1] UNIV HERTFORDSHIRE,DIV CHEM SCI,COLL LANE,HATFIELD AL10 9AB,HERTS,ENGLAND

[2] UNIV WALES COLL CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES

来源：

POLYHEDRON | 1992年 / 11卷 / 23期

关键词：

D O I：

10.1016/S0277-5387(00)80169-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and X-ray crystal structures of [(HB(pz*)3)2In]I and [(MeGa(pz)3)2In][InI4](pz = pyrazole, pz* = 3,5-dimethylpyrazole) are described. The cations of these complexes correspond to the unknown indocene cations [eta5-C5R5In]+ (R = H, Me). The indium centre has fac-fac octahedral coordination from the tridentate ligand. The In-N distances are 2.225-2.273(5) angstrom for the borate and 2.207 2.228(13) angstrom for the gallate.

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页码：3013 / 3017

页数：5

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