MECHANISM AND UTILITY OF THE DIRHENIUM DECACARBONYL CATALYZED FORMATION OF SILYL ETHERS

被引:21
作者
BARTON, DHR
KELLY, MJ
机构
[1] Department of Chemistry, Texas A and M University, College Station
关键词
D O I
10.1016/S0040-4039(00)61183-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A mechanism for dirhenium decacarbonyl catalyzed formation of silyl ethers is proposed. This reaction is a good alternative to the standard silylation procedure involving the use of more expensive silyl chlorides; even tertiary silyl ethers are readily formed.
引用
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页码:5041 / 5044
页数:4
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