POLYARYLENES AND POLYARYLENEVINYLENES .2. OLIGORYLENE AS A MODEL FOR POLY(PERINAPHTHALENE)

被引：98

作者：

BOHNEN, A

KOCH, KH

LUTTKE, W

MULLEN, K

机构：

[1] MAX PLANCK INST POLYMER RES,ACKERMANNWEG 10,W-6500 MAINZ 1,GERMANY

[2] UNIV GOTTINGEN,INST ORGAN CHEM,W-3400 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 05期

关键词：

D O I：

10.1002/anie.199005251

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rylenes are annelated arenes derived formally by coupling all the peri‐positions of naphthalene. Several soluble oligorylenes have now been synthesized as models for “polyrylene” 1. R = H. Among the most striking features to emerge in the course of characterizing the compounds were a small HOMO/ LUMO energy gap for the quaterrylene 2, R = tBu, n = 2. and a high powder conductivity for the charge‐transfer complex of the same compound. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：525 / 527

页数：3

共 16 条

[1] ON THE OBSERVED HIGH CONDUCTIVITY OF POLY-(PERINAPHTHALENE) CHAINS [J].