SYNTHESIS AND CRYSTAL-STRUCTURE OF TETRAHYDROFURFURYLCYCLOPENTADIENYL SODIUM TETRAHYDROFURANATE COMPLEX

被引：10

作者：

ZHANG, SB

LIU, JZ

WEI, GC

LIN, GY

CHEN, WQ

机构：

[1] ACAD SINICA,CHANGCHUN INST APPL CHEM,CHANGCHUN 130022,PEOPLES R CHINA

[2] JILIN UNIV,DEPT CHEM,CHANGCHUN 130023,PEOPLES R CHINA

来源：

POLYHEDRON | 1993年 / 12卷 / 23期

关键词：

D O I：

10.1016/S0277-5387(00)80057-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A tetrahydrofurfurylcyclopentadienyl sodium tetrahydrofuranate complex was prepared by the reaction of tetrahydrofurfurylcyclopentadiene with metallic sodium in THF. Its crystal structure was determined by X-ray analysis. In the crystal. the tetrahydrofuranate complex C4H7OCH2C5H4Na . THF adopts a puckered chain structure with an eta5-(C4H7OCH2)C5H4 ring connected by a bridging Na(THF) unit. The oxygen in the eta5-(C4H7OCH2)C5H4 ring is coordinated to the sodium atom.

引用

页码：2771 / 2774

页数：4

共 7 条

[1]

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[2] SYNTHESIS OF TETRAHYDROFURFURYLCYCLOPENTADIENE AND ITS THALLIUM, MANGANESE, AND RHODIUM COMPLEXES AND THE LOW-TEMPERATURE MATRIX PHOTOLYSIS OF THE MANGANESE COMPLEX [J].