DETERMINATION OF THE DOUBLE ELECTRIC LAYER PARAMETERS IN THE METAL-POLYMER ADHESION CONTACT BY THE NONDESTRUCTIVE THERMODEPOLARIZATION METHOD

被引：1

作者：

LIPSON, AG ^{[1
]}

KUZNETSOVA, EV ^{[1
]}

SAKOV, DM ^{[1
]}

DERJAGUIN, BV ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST PHYS CHEM,MOSCOW 117915,RUSSIA

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1994年 / 162卷 / 01期

关键词：

D O I：

10.1006/jcis.1994.1010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The parameters of a double electric layer (DEL) at the interface were defined on the basis of the experimental data obtained from the analysis of the spectra of thermostimulated depolarization of metal-polymer adhesive contacts. The extremum values of these parameters have been assessed, and these determine the contribution of the electrostatic component to adhesion. It has been shown that the intensity of the electric field at the interface can attain the values of ca. 107 V/cm. The ionization coefficient of the functional groups of polymer close to the adhesive contact has been evaluated (10-3-10−4). The width of the range of a space charge of the DEL in the polymer has been calculated by taking into account that value. © 1994 by Academic Press, Inc.

引用

页码：75 / 80

页数：6

共 36 条

[1] Investigation of the parameters of a double electric layer at the metal polymer adhesion contact by thermostimulated depolarization method
Lipson, A.G.
Kuznetsova, E.V.
Sakov, D.M.
Toporov, Yu.P.
Physics, Chemistry, and Mechanics of Surfaces, 1994, 8 (12):
[2] On Diagnostics of Double Electric Layer in the Zone of Metal-Polymer Adhesion Contact Using the Positron-Annihilation-Probe Method
Bardyshev, I. I.
Toporov, Yu. P.
Klyuev, V. A.
Gol'danskii, A. V.
Kotenev, V. A.
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2017, 53 (06) : 1181 - 1186
[3] PARAMETERS OF DOUBLE ELECTRICAL LAYER AND THE ADHESION IN METAL POLYMER CONTACT
LIPSON, AG
KUZNETSOVA, EV
SAKOV, DM
MOROZOVA, NI
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DOKLADY AKADEMII NAUK SSSR, 1990, 310 (06): : 1398 - 1403
[4] An experimental method for the determination of metal-polymer adhesion
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[5] On Diagnostics of Double Electric Layer in the Zone of Metal–Polymer Adhesion Contact Using the Positron-Annihilation-Probe Method
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[6] THE ELECTRIC DOUBLE-LAYER AT THE POLYMER METAL CONTACT - A PHENOMENOLOGICAL MODEL
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MULLER, I
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1988, 106 (02): : 525 - 534
[7] HIGH-RESOLUTION ULTRASONIC INTERFEROMETRY FOR QUANTITATIVE NONDESTRUCTIVE CHARACTERIZATION OF INTERFACIAL ADHESION IN MULTILAYER (METAL-POLYMER METAL) COMPOSITES
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[9] Modelling of contact and tribotechnical parameters of metal-polymer gears taking into account wear and correction of teeth
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[10] Method and results of study of metal-polymer contact joint at pre-sliding stage
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