Centrosymmetric Crystals as Host Matrices for Second-Order Optical Nonlinear Effects

被引：64

作者：

Weissbuch, I. ^{[1
]}

Lahav, M. ^{[1
]}

Leiserowitz, L. ^{[1
]}

Meredith, G. R. ^{[2
]}

Vanherzeele, H. ^{[2
]}

机构：

[1] Weizmann Inst Sci, Dept Struct Chem, IL-76100 Rehovot, Israel

[2] EI Pont Nemours & Co, Cent Res & Dev Dept, Wilmington, DE 19880 USA

来源：

CHEMISTRY OF MATERIALS | 1989年 / 1卷 / 01期

关键词：

D O I：

10.1021/cm00001a022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reduction of crystal symmetry via preferential occlusion of guest molecules through different subsets of crystal surface sites has been used to include centrosymmetric host crystals as a matrix for providing second-order nonlinear optical effects. The method is also applicable for generating a second harmonic signal along the principal nonpolar axis of polar crystals. This approach is illustrated by several examples. These optical measurements yield information on crystal growth processes and on the alignment of guest molecules in the host crystal.

引用

页码：114 / 118

页数：6

共 23 条

[1] A LINK BETWEEN MACROSCOPIC PHENOMENA AND MOLECULAR CHIRALITY - CRYSTALS AS PROBES FOR THE DIRECT ASSIGNMENT OF ABSOLUTE-CONFIGURATION OF CHIRAL MOLECULES [J].

ADDADI, L ;

BERKOVITCHYELLIN, Z ;

WEISSBUCH, I ;

LAHAV, M ;

LEISEROWITZ, L .

TOPICS IN STEREOCHEMISTRY, 1986, 16 :1-85

[2] RESOLUTION OF CONGLOMERATES BY STEREOSELECTIVE HABIT MODIFICATIONS [J].

ADDADI, L ;

BERKOVITCHYELLIN, Z ;

DOMB, N ;

GATI, E ;

LAHAV, M ;

LEISEROWITZ, L .

NATURE, 1982, 296 (5852) :21-26

[3] GROWTH AND DISSOLUTION OF ORGANIC-CRYSTALS WITH TAILOR-MADE INHIBITORS - IMPLICATIONS IN STEREOCHEMISTRY AND MATERIALS SCIENCE [J].

ADDADI, L ;

BERKOVITCHYELLIN, Z ;

WEISSBUCH, I ;

VANMIL, J ;

SHIMON, LJW ;

LAHAV, M ;

LEISEROWITZ, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (06) :466-485

[4] THE ROLE PLAYED BY C-H...O AND C-H...N INTERACTIONS IN DETERMINING MOLECULAR PACKING AND CONFORMATION [J].

BERKOVITCHYELLIN, Z ;

LEISEROWITZ, L .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1984, 40 (APR) :159-165

[5]

CHEMLA DS, 1987, NONLINEAR OPTICAL PR, V1

[6]

CHEMLA DS, 1987, NONLINEAR OPTICAL PR, V2

[7]

Eaton D. F., 1987, POLYM HIGH TECHNOLOG

[8] NONLINEAR DIELECTRIC POLARIZATION IN OPTICAL MEDIA [J].

KLEINMAN, DA .

PHYSICAL REVIEW, 1962, 126 (06) :1977-&

[9] THE STRUCTURES OF POLYMORPHS OF N-(P-DIMETHYLAMINOBENZYLIDENE)-P-NITROANILINE [J].

NAKAI, H ;

EZUMI, K ;

SHIRO, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1981, 37 (JAN) :193-197

[10] CRYSTAL AND MOLECULAR-STRUCTURES OF PARA-NITROBENZYLIDENE-PARA-DIMETHYLAMINOANILINE AND PARA-DIMETHYLAMINOBENZYLIDENE-PARA-NITROANILINE [J].

NAKAI, H ;

SHIRO, M ;

EZUMI, K ;

SAKATA, S ;

KUBOTA, T .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (JUN15) :1827-1833

← 1 2 3 →