VIBRATIONAL STUDY OF OXALIC ACID-PYRAZINE HYDROGEN-BONDED ADDUCTS

被引：13

作者：

BELABBES, Y ^{[1
]}

LAUTIE, A ^{[1
]}

机构：

[1] LASIR,CNRS,F-94320 THIAIS,FRANCE

来源：

VIBRATIONAL SPECTROSCOPY | 1995年 / 9卷 / 02期

关键词：

COMPLEXATION; HYDROGEN BONDS; INFRARED SPECTROMETRY; OXALIC ACID; PYRAZINE; RAMAN SPECTROMETRY;

D O I：

10.1016/0924-2031(94)00093-V

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Infrared and Raman spectra of anhydrous and hemi-hydrated pyrazine-oxalic acid crystallized complexes and their deuterated analogues have been investigated between 4000 and 30 cm(-1) in the 400-90 K temperature range. Pyrazine retains its high molecular symmetry and the two nitrogens are involved in the complexation. From the spectroscopic data it is found that the general pattern consists of infinite chains of alternated pyrazine and oxalic acid molecules built by OH ... N hydrogen bonds with R(OH .. N) = 2.65 Angstrom. For deuterated and hemi-hydrated derivatives, this hydrogen bond is weaker.

引用

页码：131 / 137

页数：7

共 33 条

[1] VIBRATIONAL-SPECTRA OF [H-1(4)]PYRAZINE AND [H-2(4)]PYRAZINE [J].

ARENAS, JF ;

LOPEZNAVARRETE, JT ;

OTERO, JC ;

MARCOS, JI ;

CARDENETE, A .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1985, 81 (MAR) :405-415

[2] SPECTROSCOPIC DIFFERENCES BETWEEN MOLECULAR (O-H...N) AND IONIC PAIR (O-...H-N+) HYDROGEN COMPLEXES [J].

BARCZYNSKI, P ;

DEGASZAFRAN, Z ;

SZAFRAN, M .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1985, (06) :765-771

[3] VIBRATIONAL STUDY AND PHASE-TRANSITION OF PYRIDINE OXALIC-ACID COMPLEXES [J].

BELABBES, Y ;

LAUTIE, A .

JOURNAL OF RAMAN SPECTROSCOPY, 1993, 24 (04) :237-243

[4]

BELABBES Y, 1995, THESIS U P M CURIE

[5] NATURE OF A,B,C-TYPE INFRARED SPECTRA OF STRONGLY HYDROGEN-BONDED SYSTEMS - PSEUDO-MAXIMA IN VIBRATIONAL SPECTRA [J].

CLAYDON, MF ;

SHEPPARD, N .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (23) :1431-&

[6]

de Villepin J., 1976, Journal of Molecular Structure, V30, P255, DOI 10.1016/0022-2860(76)87004-4

[7]

de Villepin J., 1978, SPECTROCHIM ACTA A, V34, P1019

[8]

de Villepin J., 1978, SPECTROCHIM ACTA A, V34, P1009

[9] VIBRATION SPECTRA OF ACID SODIUM OXALATES - ISOTOPIC EFFECT ON HYDROGEN BOND [J].

DEVILLEPIN, J ;

NOVAK, A .

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1971, A 27 (08) :1259-+

[10] MODEL CALCULATIONS OF VIBRATIONS OF BONDED WATER-MOLECULES [J].

ERIKSSON, A ;

LINDGREN, J .

JOURNAL OF MOLECULAR STRUCTURE, 1978, 48 (03) :417-430

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