MOLYBDENUM(IV) AZAMOLYBDATRANES CLMO(R(3)SINCH(2)CH(2))(3)N FROM AN UNEXPECTED REACTION

被引：27

作者：

DUAN, ZB ^{[1
]}

VERKADE, JG ^{[1
]}

机构：

[1] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 06期

关键词：

D O I：

10.1021/ic00110a040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The azamolybdatranes ClMo(Me(3)SiNCH(2)CH(2))(3)N, 2a, and ClMo(t-BuMe(2)SiNCH(2)CH(2))(3)N, 2b, were prepared by the reaction of MoCl3(THF)(3) and the corresponding lithiated tetramines. The mu(eff) for 2a is 2.35 mu(B). This compound was structurally characterized in the solid state by X-ray diffraction. Crystal data: cubic, a = 17.199(1) Angstrom, V = 5087.6(11) Angstrom(3), Z = 8, space group Pa3 $$($) over bar, R = 2.7%.

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页码：1576 / 1578

页数：3

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