STRUCTURE OF [CU(CN)(PY)2]

被引：15

作者：

OLMSTEAD, MM ^{[1
]}

SPEIER, G ^{[1
]}

SZABO, L ^{[1
]}

机构：

[1] UNIV VESZPREM,DEPT ORGAN CHEM,H-8201 VESZPREM,HUNGARY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192009326

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

catena-Poly[{bis(pyridine-N)copper(I)}-mu-cyano-N:C] crystallizes with two independent polymeric chains in the structure. The chains are propagated by -CN- groups that are N-bound and C-bound to Cu(I) centres with no apparent disorder. Each Cu is bound to two pyridines, the N atom of one CN and the C atom of another. The coordination geometry is distorted tetrahedral with particularly wide angles involving the cyanide groups.

引用

页码：370 / 372

页数：3

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