PHOTOREDOX PROPERTIES OF IRON(III) COMPLEXES CONTAINING QUADRIDENTATE SCHIFF-BASE LIGANDS

被引：0

作者：

SRAMKO, T ^{[1
]}

SIMA, J ^{[1
]}

FODRAN, P ^{[1
]}

机构：

[1] SLOVAK UNIV TECHNOL BRATISLAVA, DEPT INORGAN CHEM, RADLINSKEHO 9, CS-81237 BRATISLAVA, CZECHOSLOVAKIA

来源：

ACTA CHIMICA HUNGARICA-MODELS IN CHEMISTRY | 1992年 / 129卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron(III) complexes with an open-chain quadridentate N2O2-ligand of the type of "acacen", "salen" and "benacen" coordinated in the equatorial plane undergo a photoreduction of Fe(III) to Fe(II) when being irradiated in methanol by ultraviolet light. Quantum yields of Fe(II) formation depend on the wavelength of excitation light and on the peripheral groups of thc equatorial ligands, but they correlate neither with Taft nor Hammett parameters of the peripheral groups.

引用

页码：215 / 223

页数：9

共 16 条

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