SAMARIUM(II) IODIDE - A DIASTEREOSELECTIVE REAGENT FOR THE SYNTHESIS OF AROMATIC 1,2-DIOL STRUCTURES - MODEL REACTIONS

被引：7
作者：
WEGE, VU [1 ]
GREINER, A [1 ]
机构：
[1] ZENTRUM MAT WISSENSCH,D-35032 MARBURG,GERMANY
来源：
ACTA POLYMERICA | 1995年 / 46卷 / 05期
关键词：
D O I：
10.1002/actp.1995.010460508
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Variation of the reaction conditions for the C-C coupling reaction of aromatic carbonyl compounds to their 1,2-diol structures in the presence of samaraium(II)-iodide led to different diastereoselectivities. The molar ratio of the starting materials, substituents, and solvent variation had a significant influence on 1,2-diol formation. An interpretation of the observed results is suggested. Sterical demands of the active complex and an intramolecular samarium-oxygen interaction could lead to the diastereomer ratio obtained.
引用
收藏
页码：396 / 403
页数：8
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