A MULTINUCLEAR NMR-STUDY OF HYDROGEN-BONDING IN SOME SUBSTITUTED N-PHENYL-BENZYLIMINES

被引：0

作者：

SITKOWSKI, J

DZIEMBOWSKA, T

GRECH, E

STEFANIAK, L

WEBB, GA

机构：

[1] POLISH ACAD SCI,INST ORGAN CHEM,PL-01224 WARSAW,POLAND

[2] TECH UNIV SZCZECIN,INST FUNDAMENTAL CHEM,PL-71065 SZCZECIN,POLAND

[3] UNIV SURREY,DEPT CHEM,GUILDFORD GU2 5XH,SURREY,ENGLAND

来源：

POLISH JOURNAL OF CHEMISTRY | 1994年 / 68卷 / 12期

关键词：

HYDROGEN BONDING; N-15 NMR CHEMICAL SHIFTS; N-PHENYL-BENZYLIMINES;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

H-1, C-13 and N-15 NMR data are reported for six substituted N-phenyl-benzylimines in 0.2 m CDCl3 solutions. The observed increase oof shielding about 10 ppm for nitrogen signals support the trans structure stabilized by intramolecular hydrogen bond.

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页码：2633 / 2636

页数：4

相关论文

共 9 条

[1] A NEW ASPECT ON THE ORIGIN OF AN ANOMALOUS SUBSTITUENT EFFECT ON THE AZOMETHINE PROTON CHEMICAL-SHIFTS IN 4-SUBSTITUTED N-BENZYLIDENEANILINES [J].

AKABA, R ;

SAKURAGI, H ;

TOKUMARU, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (01) :301-303

[2] ELECTRONIC-STRUCTURES AND CONFORMATIONS OF N-BENZYLIDENEANILINES .1. ELECTRONIC ABSORPTION SPECTRAL STUDY COMBINED WITH CNDO-S CI CALCULATIONS [J].

AKABA, R ;

TOKUMARU, K ;

KOBAYASHI, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (07) :1993-2001

[3]

Calligaris M., 1987, COMPREHENSIVE COORDI, V2, P715

[4] PHOTOCHROMIC AND THERMOCHROMIC SALICYLIDENAMINES - ISOMERIZATION IN THE CRYSTAL, INFRARED IDENTITIES AND CONFORMATIONAL INFLUENCE [J].

CARLES, M ;

ELOY, D ;

PUJOL, L ;

BODOT, H .

JOURNAL OF MOLECULAR STRUCTURE, 1987, 156 (1-2) :43-58

[5] STRUCTURAL STUDIES OF ARYLAZO AND ARYLIMINO COMPOUNDS - N-15 NMR AND X-RAY CRYSTALLOGRAPHIC STUDIES OF AZO-HYDRAZO TAUTOMERISM [J].

CONNOR, JA ;

KENNEDY, RJ ;

DAWES, HM ;

HURSTHOUSE, MB ;

WALKER, NPC .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (01) :203-207

[6] STRUCTURE AND OPTICAL-PROPERTIES OF A THERMOCHROMIC SCHIFF-BASE - THERMALLY INDUCED INTRAMOLECULAR PROTON-TRANSFER IN THE N,N'-BIS(SALICYLIDENE)-PARA-PHENYLENEDIAMINE CRYSTALS [J].

HOSHINO, N ;

INABE, T ;

MITANI, T ;

MARUYAMA, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (12) :4207-4214

[7] C-13 AND H-1-NMR STUDY OF N-5'-METHYLSALICYLIDENEANILINES [J].

KISHORE, K ;

SATHYANARAYANA, DN ;

BHANU, VA .

MAGNETIC RESONANCE IN CHEMISTRY, 1987, 25 (06) :471-473

[8] A SPECTROSCOPIC STUDY OF PROTON-TRANSFER AND PHOTOCHROMISM IN N-(2-HYDROXYBENZYLIDENE)ANILINE [J].

LEWIS, JW ;

SANDORFY, C .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1982, 60 (13) :1738-1746

[9] THE C-13 CHEMICAL-SHIFTS OF 2'-HYDROXY-SUBSTITUTED N-BENZYLIDENE-ANILINES AND SOME N,N-(ORTHO-HYDROXYBENZYLIDENE)DIAMINES [J].

SALMAN, SR ;

ALRAWI, JM ;

BEHNAM, GQ .

ORGANIC MAGNETIC RESONANCE, 1984, 22 (08) :535-535