THERMODYNAMIC ORIGIN OF PROLYL PEPTIDE-BOND ISOMERS

被引:30
作者
EBERHARDT, ES [1 ]
LOH, SN [1 ]
RAINES, RT [1 ]
机构
[1] UNIV WISCONSIN,DEPT BIOCHEM,MADISON,WI 53706
关键词
D O I
10.1016/S0040-4039(00)93377-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The preference for the trans isomer of prolyl peptide bonds arises almost entirely from enthalpy in aqueous buffer and in toluene.
引用
收藏
页码:3055 / 3056
页数:2
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