A TM-169 MOSSBAUER INVESTIGATION OF TM2CU2O5

被引:6
|
作者
STEWART, GA [1 ]
CAGODAN, JM [1 ]
机构
[1] UNIV NEW S WALES,SCH PHYS,KENSINGTON,NSW 2033,AUSTRALIA
关键词
D O I
10.1016/0304-8853(93)90433-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A Tm-169 Mossbauer investigation of Tm2Cu2O5 is reported. All spectra over the temperature range 4.2-300 K are able to be analysed in terms of a single Tm site even though there are known to be 2 non-equivalent Tm sites for the Ho2Cu2O5-type structure. The Tm lattice is determined to be magnetically polarised below T(order) = 17.5 K with a site-independent moment of mu(Tm) = 3.90(8)mu(B) at 4.2 K. A 2-singlet model is proposed wherein the Tm moments are induced by a molecular field which is proportional to the Cu magnetisation. The model is consistent with canted Tm magnetism and estimates a saturation molecular field of 1.65 T to act at each Tm atom.
引用
收藏
页码:322 / 330
页数:9
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