Diarylplatinum(II) Compounds as Versatile Metallating Agents in the Synthesis of Cyclometallated Platinum Compounds with N-Donor Ligands

被引：14
作者：
Crespo, Margarita [1 ]
机构：
[1] Univ Barcelona, Fac Quim, Dept Quim Inorgan, Diagonal 645, Barcelona 08028, Spain
来源：
INORGANICS | 2014年 / 2卷 / 01期
关键词：
platinum; cyclometallation; N-donor ligands; diarylplatinum(II) precursors; synthesis;
D O I：
10.3390/inorganics2010115
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review deals with the reactions of diarylplatinum(II) complexes with N-donor ligands to produce a variety of cycloplatinated compounds including endo-five-, endo-seven-, endo-six-or exo-five-membered platinacycles. The observed reactions result from a series of oxidative addition/reductive elimination processes taking place at platinum(II)/platinum(IV) species and involving C-X (X = H, Cl, Br) bond activation, arene elimination, and, in some cases, C-aryl-C-aryl bond formation.
引用
收藏
页码：115 / 131
页数：17
相关论文
共 72 条
  • [11] Regioselective C-H Activation Preceded by Csp2-Csp3 Reductive Elimination from Cyclometalated Platinum(IV) Complexes
    Anderson, Craig M.
    Crespo, Margarita
    Kfoury, Nicole
    Weinstein, Michael A.
    Tanski, Joseph M.
    [J]. ORGANOMETALLICS, 2013, 32 (15) : 4199 - 4207
  • [12] Stereoselectivity in organometallic reactions: Oxidative addition of alkyl halides to platinum(II)
    Baar, CR
    Jenkins, HA
    Vittal, JJ
    Yap, GPA
    Puddephatt, RJ
    [J]. ORGANOMETALLICS, 1998, 17 (13) : 2805 - 2818
  • [13] Oxidative addition to diplatinum(II) complexes: Stereoselectivity and cooperative effects
    Baar, CR
    Carbray, LP
    Jennings, MC
    Puddephatt, RJ
    [J]. ORGANOMETALLICS, 2000, 19 (13) : 2482 - 2497
  • [14] Facile Metalation of Hbzq by [cis-Pt(C6F5)2(thf)2]: A Route to a Pentafluorophenyl Benzoquinolate Solvate Complex That Easily Coordinates Terminal Alkynes. Spectroscopic and Optical Properties
    Berenguer, Jesus R.
    Lalinde, Elena
    Teresa Moreno, M.
    Sanchez, Sergio
    Torroba, Javier
    [J]. INORGANIC CHEMISTRY, 2012, 51 (21) : 11665 - 11679
  • [15] New Insights in the Formation of Five- Versus Seven-Membered Platinacycles: A Kinetico-Mechanistic Study
    Bernhardt, Paul V.
    Calvet, Teresa
    Crespo, Margarita
    Font-Bardia, Merce
    Jansat, Susanna
    Martinez, Manuel
    [J]. INORGANIC CHEMISTRY, 2013, 52 (01) : 474 - 484
  • [16] Kinetico-Mechanistic Studies on Intramolecular C-X Bond Activation (X = Br, Cl) of Amino-Imin Ligands on Pt(II) Compounds. Prevalence of a Concerted Mechanism in Nonpolar, Polar, and Ionic Liquid Media
    Calvet, Teresa
    Crespo, Margarita
    Font-Bardia, Merce
    Jansat, Susanna
    Martinez, Manuel
    [J]. ORGANOMETALLICS, 2012, 31 (11) : 4367 - 4373
  • [17] Kinetico-Mechanistic Insight into the Platinum-Mediated C-C Coupling of Fluorinated Arenes
    Calvet, Teresa
    Crespo, Margarita
    Font-Bardia, Merce
    Gomez, Kerman
    Gonzalez, Gabriel
    Martinez, Manuel
    [J]. ORGANOMETALLICS, 2009, 28 (17) : 5096 - 5106
  • [18] Facial and meridional [N-C-N]- intramolecular coordination systems:: structure of fac-PtBrMe2{2,6-(pzCH2)2C6H3}•1/2C6H6{[2,6-(pzCH2)2C6H3]-=2,6-(bis{(pyrazol-1-yl)methyl}phenyl)} and mer-PtBr{2,6-(3,5-Me2pzCH2)2C6H3}, and an alternative synthetic route to the platinum(II) [N-C-N]- kernel
    Canty, AJ
    Patel, J
    Skelton, BW
    White, AH
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 599 (02) : 195 - 199
  • [19] Capape A, 2007, DALTON T, P2030, DOI 10.1039/b618128g
  • [20] Exploring the Versatility of Cycloplatinated Thiosemicarbazones as Antitumor and Antiparasitic Agents
    Chellan, Prinessa
    Land, Kirkwood M.
    Shokar, Ajit
    Au, Aaron
    An, Seung Hwan
    Clavel, Catherine M.
    Dyson, Paul J.
    de Kock, Carmen
    Smith, Peter J.
    Chibale, Kelly
    Smith, Gregory S.
    [J]. ORGANOMETALLICS, 2012, 31 (16) : 5791 - 5799
12345678