MERCURY-PHOTOSENSITIZED SULFINATION, HYDROSULFINATION, AND CARBONYLATION OF HYDROCARBONS - ALKANE AND ALKENE CONVERSION TO SULFONIC-ACIDS, KETONES, AND ALDEHYDES

被引：45
作者：
FERGUSON, RR [1 ]
CRABTREE, RH [1 ]
机构：
[1] YALE UNIV,DEPT CHEM,225 PROSPECT ST,NEW HAVEN,CT 06511
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 19期
关键词：
D O I：
10.1021/jo00019a006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Mercury-photosensitized sulfination of alkanes, RH, with SO2 forms sulfinic acids (RSOOH) and sulfinate esters (RSOOR) in high conversion and yield; oxidation of the mixture produces RSO2OH in high yield. Mercury-photosensitized hydrosulfination of alkenes with H2 and SO2 gives RSO2OH after oxidative workup. Mercury-photosensitized carbonylation of alkanes with CO gives RCHO and R2CO.
引用
收藏
页码：5503 / 5510
页数：8
相关论文
共 90 条
[31]   PHOTO-CHEMICAL EXTRUSION OF SULFUR-DIOXIDE FROM SULTINES [J].
DURST, T ;
HUANG, JC ;
SHARMA, NK ;
SMITH, DJH .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1978, 56 (04) :512-516
[32]   BIRADICAL TRAPPING WITH SULPHUR DIOXIDE - SULPHINIC ACIDS FROM PHOTOREACTION OF TERT-BUTYL-PARA BENZOQUINONES WITH SULPHUR DIOXIDE [J].
FARID, S .
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (02) :73-&
[33]  
FERGUSON RR, 1989, NEW J CHEM, V13, P647
[34]  
FERGUSON RR, 1989, HETEROCYCLES, V28, P121
[35]   TELOMERS FROM CARBON MONOXIDE AND OLEFINS [J].
FOSTER, RE ;
LARCHAR, AW ;
LIPSCOMB, RD ;
MCKUSICK, BC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (21) :5606-5611
[36]   ORGANIC RADICAL-RADICAL REACTIONS - DISPROPORTIONATION VS COMBINATION [J].
GIBIAN, MJ ;
CORLEY, RC .
CHEMICAL REVIEWS, 1973, 73 (05) :441-464
[37]  
Gilbert E.E., 1965, SULFONATION RELATED
[38]   ABSORPTION COEFFICIENTS OF SULFUR DIOXIDE IN VACUUM ULTRAVIOLET [J].
GOLOMB, D ;
WATANABE, K ;
MARMO, FF .
JOURNAL OF CHEMICAL PHYSICS, 1962, 36 (04) :958-&
[39]   LOW-TEMPERATURE FREE-RADICAL REACTIONS INITIATED WITH TERT-BUTYL PARA-BENZOYLPERBENZOATE - SELECTIVE ACYL RADICAL ADDITIONS TO SUBSTITUTED OLEFINS [J].
GOTTSCHALK, P ;
NECKERS, DC .
JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (19) :3498-3502
[40]  
GOUDIE RS, 1971, J CHEM SOC C, P1251
123456789