ROBINSON ANNULATION ON A CARBOHYDRATE DERIVATIVE

被引：19

作者：

BONNERT, RV ^{[1
]}

HOWARTH, J ^{[1
]}

JENKINS, PR ^{[1
]}

LAWRENCE, NJ ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 05期

关键词：

D O I：

10.1039/p19910001225

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of an enolate derived from methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-alpha-D-arabinohexopyranosid-2-ulose have been studied; examples of O-alkylation, C-alkylation and Robinson annulation were observed. In the latter case the structure of the product was confirmed by X-ray crystallography on a crystalline allylic alcohol prepared by reduction of the ketone produced in the reaction.

引用

页码：1225 / 1229

页数：5

共 22 条

[1]

Boeckman R. K., 1978, ORG SYNTH, V58, P152

[2] THE 1ST EXAMPLE OF A ROBINSON ANNULATION ON A CARBOHYDRATE DERIVATIVE [J].