LIGAND-METAL INTERACTIONS AND EXCITED-STATE PROPERTIES IN RUTHENIUM(II)-DIIMINE COMPLEXES

被引：19
作者：
AKASHEH, TS
JIBRIL, I
SHRAIM, AM
机构：
[1] Chemistry Department, Yarmouk University, Irbid
来源：
INORGANICA CHIMICA ACTA | 1990年 / 175卷 / 02期
关键词：
D O I：
10.1016/S0020-1693(00)84824-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
2,2′-Bipyridine (bpy); 2,2′-bipyrazine (bpz); 5,6-dimethyl-2,3-di-(2′-pyridyl)-quinoxaline (dbpq); 4,4′- dimethyl-2,2′-bipyridine (dmbpy), 2,3-di-(2′- pyridyl)-pyrazine (dpp); 3,3′-bipyridazine (bpd); 2,3-di-(2′- pyridyl)-quinoxaline (dpq) and 2-(2′-pyridyl)-quinoline (pyq) form mixed-ligand complexes with Ru(II). The excited state properties (emission, lifetimes and redox potentials) are reported and analyzed in the framework of solar energy conversion. Ligand σ- and π-bonding properties are also deduced. © 1990.
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页码：171 / 180
页数：10
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