UNUSUAL DOUBLE PALLADIUM(II) CYCLOMETALATION IN A TWEETER-LIKE RECEPTOR WITH STACKED ARMS - SYNTHESIS, PROPERTIES AND X-RAY STRUCTURE

被引：14

作者：

AGNUS, Y ^{[1
]}

GROSS, M ^{[1
]}

LABARELLE, M ^{[1
]}

LOUIS, R ^{[1
]}

METZ, B ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST CHIM,CNRS,URA 405,F-67008 STRASBOURG,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 08期

关键词：

D O I：

10.1039/c39940000939

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Double metallation of L(1) via aliphatic carbon and amide nitrogen atoms results in the formation of a tweezer-like molecule 1 with a four-membered Pd-C*-C(O)-N ring and a helical configuration around the metal.

引用

页码：939 / 940

页数：2

共 16 条

[1]

BRESCHEID R, 1991, J CHEM SOC CHEM COMM, P1364

[2] BINDING OF NUCLEOSIDES, NUCLEOTIDES AND ANIONIC PLANAR SUBSTRATES BY BIS-INTERCALAND RECEPTOR MOLECULES [J].

CLAUDE, S ;

LEHN, JM ;

SCHMIDT, F ;

VIGNERON, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (17) :1182-1185

[3] 2ND-SPHERE COORDINATION - A NOVEL ROLE FOR MOLECULAR RECEPTORS [J].

COLQUHOUN, HM ;

STODDART, JF ;

WILLIAMS, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1986, 25 (06) :487-507

[4] CYCLOMETALLATED COMPOUNDS [J].

DEHAND, J ;

PFEFFER, M .

COORDINATION CHEMISTRY REVIEWS, 1976, 18 (03) :327-352

[5] COMPLEXATION OF NEUTRAL MOLECULES BY CYCLOPHANE HOSTS [J].

DIEDERICH, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (03) :362-386

[6] COMPARATIVE REACTIVITIES OF HYDROCARBON C-H BONDS WITH A TRANSITION-METAL COMPLEX [J].

JONES, WD ;

FEHER, FJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (03) :91-100

[7] MOLECULAR RECOGNITION OF NUCLEOBASES VIA SIMULTANEOUS 1ST-SPHERE AND 2ND-SPHERE COORDINATION [J].

KICKHAM, JE ;

LOEB, SJ ;

MURPHY, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (15) :7031-7032

[8] A WERNER-TYPE ALKYL COBALT(III) COMPOUND - FORMATION OF A CARBON COBALT BOND DEMONSTRATED BY C-13, CO-59 NMR AND X-RAY STRUCTURE DETERMINATIONS [J].

KOFOD, P ;

LARSEN, E ;

LARSEN, S ;

PETERSEN, CH ;

SPRINGBORG, J ;

WANG, DN .

ACTA CHEMICA SCANDINAVICA, 1992, 46 (09) :841-853

[9]

LABARELLE M, 1991, THESIS U L PASTEUR S

[10]

MACPARTLIN EM, 1969, ACTA CRYSTALLOGR B, V25, P1659

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