SYNTHESIS AND CHARACTERIZATION OF MONOMERIC, DIMERIC AND POLYMERIC FERROCENYLACETYLIDES - CRYSTAL-STRUCTURE OF 1,1'-BIS(PHENYLETHYNYL)FERROCENE

被引：65

作者：

INGHAM, SL ^{[1
]}

KHAN, MS ^{[1
]}

LEWIS, J ^{[1
]}

LONG, NJ ^{[1
]}

RAITHBY, PR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 470卷 / 1-2期

关键词：

FERROCENE; TIN; ALKYNE; CRYSTAL STRUCTURE; POLYMER;

D O I：

10.1016/0022-328X(94)80160-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of alkynyltrimethylstannanes with 1,1'-dilithioferrocene have given several ferrocenylacetylides, namely 1-phenyl-ethynyl-1'-iodo-ferrocene (1) 1,1'-bis(phenylethynyl)ferrocene (2), 1,4-di(1'-iodoferrocenylethynyl)benzene (3) and poly[1,4-(1'-ferrocenylethnyl)ethynlbenzene] (4). The versatility of this reaction for the formation of ferrocenylacetylides is demonstrated. The crystal structure of 2 has been determined, and shown to involve a linear array of the groups with a cis arrangement of the phenylethynyl ligands.

引用

页码：153 / 159

页数：7

共 34 条

[1] THE SYNTHESES, STRUCTURES, AND STEREODYNAMICS OF [3]FERROCENOPHANE COMPLEXES .1. GROUP-6 METAL TETRACARBONYL COMPLEXES, CIS-[M(CO)4((C5H4ECH3)2FE)] - (M = CR, MO, W-E = S OR SE) - CRYSTAL-STRUCTURE OF 1,1'-BIS(METHYLSELENO) FERROCENE TETRACARBONYLTUNGSTEN [J].

ABEL, EW ;

LONG, NJ ;

ORRELL, KG ;

OSBORNE, AG ;

SIK, V ;

BATES, PA ;

HURSTHOUSE, MB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 367 (03) :275-289

[2] THE SYNTHESES, STRUCTURES AND STEREODYNAMICS OF TRANSITION-METAL COMPLEXES OF 1,1'-BIS(METHYLTHIO)RUTHENOCENE - CRYSTAL-STRUCTURE OF 1,1'-BIS(METHYLTHIO)RUTHENOCENE TETRACARBONYLTUNGSTEN [J].

ABEL, EW ;

LONG, NJ ;

ORRELL, KG ;

OSBORNE, AG ;

SIK, V ;

BATES, PA ;

HURSTHOUSE, MB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 394 (1-3) :455-468

[3]

ABEL EW, 1990, J ORGANOMET CHEM, V383, P25

[4] SYNTHESIS OF FERROCENYLACETYLENES [J].

ABRAM, TS ;

WATTS, WE .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1976, 6 (01) :31-53

[5]

[Anonymous], 1992, INORGANIC MAT

[6] RIGID-ROD SIGMA-ACETYLIDE COMPLEXES OF IRON, RUTHENIUM AND OSMIUM [J].

ATHERTON, Z ;

FAULKNER, CW ;

INGHAM, SL ;

KAKKAR, AK ;

KHAN, MS ;

LEWIS, J ;

LONG, NJ ;

RAITHBY, PR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 462 (1-2) :265-270

[7] SYNTHESIS, CHARACTERIZATION AND CRYSTAL-STRUCTURE OF 2-DICYANOMETHYLENE-1,3-BIS(FERROCENYLMETHYL)-1,3-DIAZOLIDINE [J].

BENITO, A ;

CANO, J ;

MARTINEZMANEZ, R ;

PAYA, J ;

SOTO, J ;

JULVE, M ;

LLORET, F ;

MARCOS, MD ;

SINN, E .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (13) :1999-2003

[8]

CHI KM, 1991, ORGANOMETALLICS, V10, P668

[9]

CONSTABLE EC, 1992, ORGANOMETALLIC CHEM, V21, P338

[10] SYNTHESIS OF MONOMERIC AND OLIGOMERIC BIS(ACETYLIDE) COMPLEXES OF PLATINUM AND RHODIUM [J].

DAVIES, SJ ;

JOHNSON, BFG ;

KHAN, MS ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (03) :187-188

← 1 2 3 4 →