PHOTOPOLYMERIZATION OF VINYL MONOMERS USING BENZOPHENONE-TETRAHYDROFURAN INITIATION SYSTEM AND ALDEHYDES AT LOW-TEMPERATURES

被引：7

作者：

MATSUZAWA, S

YAMAURA, K

YAMADA, S

SHINKE, Y

NAKANO, Y

KOIKE, Y

机构：

[1] Shinshu Univ, Ueda, Jpn, Shinshu Univ, Ueda, Jpn

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1988年 / 35卷 / 02期

关键词：

POLYMERIZATION - POLYMETHYL METHACRYLATE - Synthesis;

D O I：

10.1002/app.1988.070350208

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The photopolymerizations of vinyl trifluoroacetate (VTFAc), vinyl acetate (VAc), and methyl methacrylate (MMA) using the initiation system benzophenone-tetrahydrofuran were studied at low temperatures. At minus 78 degree C the rate of polymerization of VTFAc was higher than that of VAc, while MMA, which was solidified, did not polymerize. After melting the irradiated solid mixture the polymerization occurred at 4 degree C. The photoinduced polymerization of VTFAc occurred in the presence of butylaldehyde or isobutylaldehyde at minus 70 degree C. The degrees of polymerization and syndiotacticities of the polymers prepared were investigated.

引用

页码：391 / 396

页数：6

共 13 条

[1] ALDEHYDE PEROXIDES AS INITIATORS FOR POLYMERIZATION OF ACRYLONITRILE [J].