THE CLEAVAGE OF A COORDINATED SCNR GROUP IN [FE(CO)(2)L(2)(ETA(2)-SCNR)] BY [CO(ETA-C5H5)(PPH(3))(2)] TO GIVE COMPLEXES CONTAINING MU(3)-CNR LIGAND - THE PREPARATION AND STRUCTURE OF [(CO(ETA-C5H5))(2)(FE(CO)(2)(PPH(3)))(MU(3)-S)(MU(3)-CNC(O)C6H5)]

被引：5

作者：

MANNING, AR ^{[1
]}

ODWYER, L ^{[1
]}

MCARDLE, PA ^{[1
]}

CUNNINGHAM, D ^{[1
]}

机构：

[1] UNIV COLL GALWAY,DEPT CHEM,GALWAY,IRELAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 503卷 / 02期

关键词：

COBALT; IRON; MU-3-ISOCYANIDE; MU-3-CARBONYL; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(95)05863-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Fe(CO)(2)(PPh(3))(2){eta(2)-SCNC(O)Ph}] with [Co(eta-C5H5)(PPh(3))(2)] in benzene solution at room temperature results in the facile cleavage of the C-S bond of the SCNC(O)Ph ligand to give [{Co(eta-C5H5)}(2){Fe(CO)(2)(PPh(3))}(mu(3)-S){mu(3)-CNC(O)Ph}], whereas [Fe(CO)(2)(PPh(3))(2)(eta(2)-SCNMe)] gives [{Co(eta-C5H5)}(2){Fe(CO)(CNMe)(PPh(3))}(mu(3)-S)(mu(3)-CO)]. The structure of [{Co(eta-C5H5)}(2){Fe(CO)(2)(PPh(3))}(mu(3)-S){mu(3)-CNC(O)Ph}] has been confirmed by X-ray diffraction.

引用

页码：C46 / C47

页数：2

共 7 条

[1]

ASHTON H, 1982, INORG CHIM ACTA, V71, P163

[2] THE SYSTEMATIC SYNTHESIS OF COMPLEXES CONTAINING MU-CS LIGANDS AS 2-ELECTRON DONORS - THE PREPARATION AND STRUCTURE OF [(CO(ETA-C5H5))2(FE(PPH3)(CO)2)(MU-3-S)(MU-3-CS)] [J].