NONLINEAR EFFECTS IN THE REDUCTION OF ACETOPHENONE BY DIISOPINOCAMPHENYL CHLOROBORANE - INFLUENCE OF THE REAGENT PREPARATION

被引：16

作者：

GIRARD, C ^{[1
]}

KAGAN, HB ^{[1
]}

机构：

[1] UNIV PARIS 11,CNRS,SYNTH ASYMETR LAB,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 08期

关键词：

D O I：

10.1016/0957-4166(95)00242-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A nonlinear effect (NLE) in the relation between the e.e.'s of diisopinocampheyl chloroborane (EE(aux)) and the e.e.'s of 1-phenylethanol (EE(prod)) was found during the reduction of acetophenone using this chloroborane derived from mixtures of alpha-pinenes. Furthermore, this effect was a function of the preparation method of the borane precursor.

引用

页码：1881 / 1884

页数：4

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