AN OXOMETALLATE WITH THE STRUCTURE OF THE HEXAGONAL LOW-TEMPERATURE FORM OF LIFESNO4 - (CU,ZN)4ALTAO8

被引：1

作者：

HARNEIT, O

MULLERBUSCHBAUM, H

机构：

[1] Institut für Anorganische Chemie der Christian-Albrechts-Universität, W-2300 Kiel

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1992年 / 184卷 / 02期

关键词：

421 Strength of Building Materials; Mechanical Properties - 531 Metallurgy and Metallography - 804 Chemical Products Generally - 932 High Energy Physics; Nuclear Physics; Plasma Physics;

D O I：

10.1016/0925-8388(92)90506-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Single crystals of (Cu, Zn)4AlTaO8 were prepared by solid state reaction at 1300-degrees-C. X-ray investigations showed hexagonal symmetry, space group C-6v(4)-P6(3)mc; a = 5.994 angstrom; c = 9.954 angstrom; Z = 2. There is a statistical distribution of Zn2+ and Cu2+ ions, and of Cu2+ and Al3+ ions, coordinated respectively by six or four O2- ions forming octahedra or tetrahedra. A three-dimensional network of [(Cu, Zn)4AlO8]5- ions encloses isolated octahedrally coordinated Ta5+ ions. The crystal structure is of the low temperature LiFeSnO4 type.

引用

页码：323 / 328

页数：6

共 19 条

[1] NEW ORDINATE COMPACT HEXAGONAL STRUCTURE - SN2.8LI1.6M1.6O8 OXIDES WITH X=SN(TI)+M+LI AND M=ZN,MG [J].