REACTIVITY AND CATALYTIC ACTIVITY OF [RUBR2(ME2SO)3]

被引：5

作者：

PAUL, BC ^{[1
]}

SARMA, UC ^{[1
]}

PODDAR, RK ^{[1
]}

机构：

[1] NE HILL UNIV,DEPT CHEM,SHILLONG 793003,MEGHALAYA,INDIA

来源：

INORGANICA CHIMICA ACTA | 1991年 / 179卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)85367-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[RuBr2(Me2SO)3] has been used as precursor for the synthesis of many ruthenium(II) complexes containing bromide ion and other ligands. The complexes, thus synthesised are: [RuBr2L4] (L = PPh3, L2 = phen or bpy); [RuBr2(Me2SO)2L2] (L = py, AsPh3; L2 = phen, bpy or o-phenylenediamine); [RuBr2(CS)(PPh3)3]; [RuBr2(CS)(Me2SO)2]; [RuBr2(CS)(AsPh3)2(Me2SO)] and [RuBr(C2O4H)(Me2SO)2]. These compounds have been characterised with the help of analytical data and various physical methods. [RuBr2(Me2SO)3] has been used as a catalyst for the oxidation of PPh3 by molecular oxygen.

引用

页码：17 / 23

页数：7

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