METAL-ION-INDUCED SELF-ASSEMBLY OF FUNCTIONALIZED 2,6-OLIGOPYRIDINES .1. LIGAND DESIGN, SYNTHESIS, AND CHARACTERIZATION

被引:110
作者
POTTS, KT
RAIFORD, KAG
KESHAVARZK, M
机构
[1] Department of Chemistry, Rensselaer Polytechnic Institute, Troy
关键词
D O I
10.1021/ja00060a029
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthetic sequences utilizing alpha-oxoketene dithioacetal and enolate chemistry have been developed for the preparation of new functionalized bipyridines, terpyridines, quaterpyridines, quinquepyridines, sexipyridines, septipyridines, octipyridines, novipyridines, and decipyridines. Obtained in moderate to good yields, these oligopyridines were characterized by analytical and spectral data and, for sexipyridine, by X-ray crystallography.
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页码:2793 / 2807
页数:15
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