CHARGE-MOSAIC MEMBRANE FROM GAMMA-IRRADIATED POLY(STYRENE-BUTADIENE-4-VINYLPYRIDINE) TRIBLOCK COPOLYMER

被引：14

作者：

LIANG, L

YING, SK

机构：

[1] Institute of Materials Science and Engineering, East China University of Chemical Technology, Shanghi, P. O. Box 289

来源：

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 1993年 / 31卷 / 09期

关键词：

BLOCK COPOLYMER; CHARGE-MOSAIC MEMBRANE; IRRADIATION; POLY(STYRENE-BUTADIENE-4-VINYLPYRIDINE);

D O I：

10.1002/polb.1993.090310902

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(styrene-butadiene-4-vinylpyridine) triblock copolymers were prepared from styrene (S), butadiene (B), and 4-vinylpyridine (P) by sequential anionic polymerization with n-butyllithium as initiator and benzene as solvent. The triblock copolymer was characterizated by gel-permeation chromatography (GPC), transmission electron microscopy (TEM), and viscoelastic spectrometry. Films of the triblock copolymer cast from solution in mixtures of chloroform and n-butyraldehyde were subjected to gamma-ray irradiation to form cross-linked networks. Cationic and anionic groups were introduced by sulfonation and quaternization to obtain charge-mosaic membranes. The resulting membrane had substantial cation-exchange and anion-exchange capacities. The membranes were very permeable to electrolyte (J(KCl) = 2.10 X 10(-8) mol/cm2 s). (C) 1993 John Wiley & Sons, Inc.

引用

页码：1075 / 1081

页数：7