1-AZADIENE COMPLEXES OF ZIRCONOCENE

被引：37

作者：

DAVIS, JM

WHITBY, RJ

JAXACHAMIEC, A

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

[2] GLAXO GRP RES LTD,GREENFORD UB6 0HE,MIDDX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 24期

关键词：

D O I：

10.1039/c39910001743

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-Azadiene complexes of zirconocene were prepared by ligand exchange between zirconocene butene and the 1-azadiene, and by a C-H activation route from allylic amines; they are best described as 1-zircona-2-azacyclopent-3-enes and 5-unsubstituted examples are fluxional.

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页码：1743 / 1745

页数：3

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