Anodic polymerization of difluorenyls linked with polyether or alkyl spacers: Synthesis of polyfluorenes with potential complexing properties

被引：19

作者：

RaultBerthelot, J

Massaoudi, M

LeDeit, H

Simonet, J

机构：

[1] Laboratoire d'Electrochimie Organique, URA CNRS 439, Université de Rennes I, 35042 Rennes Cedex, Campus Beaulieu, avenue General Leclerc

来源：

SYNTHETIC METALS | 1995年 / 75卷 / 01期

关键词：

polymerization; difluorenyls; synthesis; polyfluorenes;

D O I：

10.1016/0379-6779(95)03380-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrochemical synthesis of new polydifluorenyls bearing polyether or alkyl substituents is described. The polymerization process (in terms of yield and mechanism) is discussed, as well as the electrochemical behavior and the physicochemical properties of the new polymers. Their affinity with K+, Na+ and Cs+ is pointed out when analyzing the reduction of poly(IV) or the reduction of a bilayer of polybenzhy-drylidenefluorene/poly(I, II, III or IV).

引用

页码：11 / 23

页数：13

共 22 条

[1]

Bard A. J., 1983, ELECTROCHIMIE PRINCI

[2] ELECTROCHEMICAL STUDIES OF BENZO-15-CROWN-5 SUBSTITUTED POLY(PYRROLE) FILMS [J].

BARTLETT, PN ;

BENNISTON, AC ;

CHUNG, LY ;

DAWSON, DH ;

MOORE, P .

ELECTROCHIMICA ACTA, 1991, 36 (08) :1377-1379

[3] EXCHANGERS WITH MONOBENZOCRYPTATE K[2B.2.2.] AS ANCHOR GROUP [J].

BLASIUS, E ;

MAURER, PG .

JOURNAL OF CHROMATOGRAPHY, 1976, 125 (03) :511-516

[4] SYNTHESIS, CRYSTAL-STRUCTURE, AND ABSORPTION-SPECTROSCOPY OF A CARBAZOLE DINITROFLUORENE BICHROMOPHORE - IDENTITY OF GROUND-STATE MOLECULAR-INTERACTIONS IN THE SINGLE-CRYSTAL AND AGGREGATES IN SOLUTION [J].

BRISSE, F ;

DUROCHER, G ;

GAUTHIER, S ;

GRAVEL, D ;

MARQUES, R ;

VERGELATI, C ;

ZELENT, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (21) :6579-6586

[5] ON THE CRYSTAL AND MOLECULAR STRUCTURE OF FLUORENE [J].

BROWN, GM ;

BORTNER, MH .

ACTA CRYSTALLOGRAPHICA, 1954, 7 (01) :139-139

[6] NEW CONDUCTING POLYMERS OBTAINED BY ANODIC-OXIDATION OF ETHERS DISUBSTITUTED BENZENE [J].

GACHE, Y ;

SIMONET, J .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1992, 89 (05) :1027-1035

[7]

GACHE Y, 1993, THESIS U RENNES 1

[8] PREPARATION OF SOME POLYMER-SUPPORTED CROWN ETHERS AND THEIR USE AS PHASE-TRANSFER CATALYSTS [J].

HODGE, P ;

KHOSHDEL, E ;

WATERHOUSE, J .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1984, (11) :2451-2455

[9] RESOLUTION OF FREE AROMATIC AMINO-ACID ENANTIOMERS BY HOST GUEST COMPLEXATION USING REVERSED-PHASE LIQUID-CHROMATOGRAPHY [J].

JOLY, JP ;

MOLL, N .

JOURNAL OF CHROMATOGRAPHY, 1990, 521 (01) :134-140

[10]

LEBERRE V, 1985, NOUV J CHIM, V9, P419

← 1 2 3 →