ACETYLENIC DERIVATIVES OF FE-2(CO)(6)(MU-SE-2) - SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF [(CO)(6)FE-2(MU-SEC(H)=C(H)SE)] AND [((CO)(6)FE2SE2)(2)(MU-C(H)-C(H))]

被引：15

作者：

MATHUR, P ^{[1
]}

DASH, AK ^{[1
]}

HOSSAIN, MM ^{[1
]}

SATYANARAYANA, CVV ^{[1
]}

机构：

[1] INDIAN INST TECHNOL, CTR REG SOPHISTICATED INSTRUMENTAT, BOMBAY 400076, MAHARASHTRA, INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

IRON; SELENIUM;

D O I：

10.1016/0022-328X(94)05350-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new acetylenic derivatives [(CO)(6)Fe-2{mu-SeC(H)=C(H)Se}] and [{(CO)(6)Fe2Se2}(2){mu-C(H)-C(H)}] have been isolated from the room-temperature reaction of Fe-2(CO)(6)(mu-Se-2) with acetylene in methanol solvent containing sodium acetate. The products have been characterized by IR and H-1, C-13 and Se-77 NMR spectroscopy. The NMR spectroscopic features of the related phenylacetylene derivatives[(CO)(6)Fe-2{mu-SeC(Ph)=C(H)Se}] and [{(CO)(6)Fe2Se2}(2){mu-C(Ph)-C(H)}] are also reported.

引用

页码：257 / 260

页数：4

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