SYNTHESIS AND STRUCTURE OF A C2-SYMMETRIC, DOUBLY BRIDGED ANSA-TITANOCENE COMPLEX

被引：38

作者：

GROSSMAN, RB ^{[1
]}

TSAI, JC ^{[1
]}

DAVIS, WM ^{[1
]}

GUTIERREZ, A ^{[1
]}

BUCHWALD, SL ^{[1
]}

机构：

[1] MIT, DEPT CHEM, CAMBRIDGE, MA 02139 USA

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 10期

关键词：

D O I：

10.1021/om00022a026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A chiral, doubly bridged ansa-titanocene complex with C2 symmetry has been synthesized in four steps from bicyclo[3.3.1]nonane-2,6-dione. The design of the complex precludes the formation of meso or C1 diastereomers or conformers.

引用

页码：3892 / 3896

页数：5

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