METAL EXCHANGED LAYERED ZIRCONIUM HYDROGEN PHOSPHATE AS BASE CATALYST OF THE MICHAEL REACTION

被引：26

作者：

COSTANTINO, U ^{[1
]}

MARMOTTINI, F ^{[1
]}

CURINI, M ^{[1
]}

ROSATI, O ^{[1
]}

机构：

[1] UNIV PERUGIA,FAC FARM,IST CHIM ORGAN,I-06123 PERUGIA,ITALY

来源：

CATALYSIS LETTERS | 1993年 / 22卷 / 04期

关键词：

LAYERED ZIRCONIUM PHOSPHATE; HETEROGENEOUS BASE CATALYSIS; MICHAEL ADDITION;

D O I：

10.1007/BF00807241

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Layered zirconium hydrogen phosphate, exfoliated by intercalation of propylamine and then exchanged with alkali metal ions has proved to be an excellent catalyst for Michael addition of beta-dicarbonyl compounds. The reactions occur with high yield, in mild conditions and with ease of work up. The catalyst, recovered from the reaction vessel, may be reused several times.

引用

页码：333 / 336

页数：4

共 17 条

[11] CATALYTIC ACTIVITY OF ZIRCONIUM-PHOSPHATE AND SOME DERIVED PHASES IN THE DEHYDRATION OF ALCOHOLS AND ISOMERIZATION OF BUTENES [J].

LAGINESTRA, A ;

PATRONO, P ;

BERARDELLI, ML ;

GALLI, P ;

FERRAGINA, C ;

MASSUCCI, MA .

JOURNAL OF CATALYSIS, 1987, 103 (02) :346-356

[12]

LASZLO P, 1990, TETRAHEDRON LETT, V34, P4867

[13]

MARMOTTINI F, 1993, MULTIFUNCTIONAL MESO, P37

[14] SURFACE-MEDIATED SOLID-PHASE REACTION - DRAMATIC IMPROVEMENT OF MICHAEL REACTION ON THE SURFACE OF ALUMINA [J].

RANU, BC ;

BHAR, S .

TETRAHEDRON, 1992, 48 (07) :1327-1332

[15] SURFACE-MEDIATED SOLID-PHASE MICHAEL REACTION - DRAMATIC ACCELERATION ON ALUMINA [J].

RANU, BC ;

BHAR, S ;

SARKAR, DC .

TETRAHEDRON LETTERS, 1991, 32 (24) :2811-2812

[16] STRUCTURE AND SURFACE-CHEMISTRY OF CRYSTALLINE ZIRCONIUM-PHOSPHATE CATALYSTS [J].

SEGAWA, K ;

NAKATA, S ;

ASAOKA, S .

MATERIALS CHEMISTRY AND PHYSICS, 1987, 17 (1-2) :181-200

[17] POTASSIUM FLUORIDE ON ALUMINA - AN EFFICIENT SOLID BASE FOR ELIMINATION, ADDITION, AND CONDENSATION [J].

YAMAWAKI, J ;

KAWATE, T ;

ANDO, T ;

HANAFUSA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1983, 56 (06) :1885-1886

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