METAL EXCHANGED LAYERED ZIRCONIUM HYDROGEN PHOSPHATE AS BASE CATALYST OF THE MICHAEL REACTION

被引：26

作者：

COSTANTINO, U ^{[1
]}

MARMOTTINI, F ^{[1
]}

CURINI, M ^{[1
]}

ROSATI, O ^{[1
]}

机构：

[1] UNIV PERUGIA,FAC FARM,IST CHIM ORGAN,I-06123 PERUGIA,ITALY

来源：

CATALYSIS LETTERS | 1993年 / 22卷 / 04期

关键词：

LAYERED ZIRCONIUM PHOSPHATE; HETEROGENEOUS BASE CATALYSIS; MICHAEL ADDITION;

D O I：

10.1007/BF00807241

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Layered zirconium hydrogen phosphate, exfoliated by intercalation of propylamine and then exchanged with alkali metal ions has proved to be an excellent catalyst for Michael addition of beta-dicarbonyl compounds. The reactions occur with high yield, in mild conditions and with ease of work up. The catalyst, recovered from the reaction vessel, may be reused several times.

引用

页码：333 / 336

页数：4

共 17 条

[1] SYNTHESES, CRYSTALLINE-STRUCTURE, AND ION-EXCHANGE PROPERTIES OF INSOLUBLE ACID SALTS OF TETRAVALENT METALS AND THEIR SALT FORMS [J].

ALBERTI, G .

ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (04) :163-170

[2] INORGANIC ION-EXCHANGE PELLICLES OBTAINED BY DELAMINATION OF ALPHA-ZIRCONIUM PHOSPHATE CRYSTALS [J].

ALBERTI, G ;

CASCIOLA, M ;

COSTANTINO, U .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1985, 107 (01) :256-263

[3] CRYSTALLINE INSOLUBLE SALTS OF POLYBASIC METALS .2. SYNTHESIS OF CRYSTALLINE ZIRCONIUM OR TITANIUM PHOSPHATE BY DIRECT PRECIPITATION [J].

ALBERTI, G ;

TORRACCA, E .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1968, 30 (01) :317-&

[4]

ALBERTI G, 1991, INCLUSION COMPOUNDS, V5, P136

[5] ZIRCONIUM AND TITANIUM PHOSPHATES AS CATALYSTS - A REVIEW [J].

CLEARFIELD, A ;

THAKUR, DS .

APPLIED CATALYSIS, 1986, 26 (1-2) :1-26

[6] CRYSTALLOGRAPHY AND STRUCTURE OF ALPHA-ZIRCONIUM BIS(MONOHYDROGEN ORTHOPHOSPHATE) MONOHYDRATE [J].

CLEARFIELD, A ;

SMITH, GD .

INORGANIC CHEMISTRY, 1969, 8 (03) :431-+

[7] FACTORS DETERMINING ION-EXCHANGE SELECTIVITY .1. HIGH-TEMPERATURE PHASES FORMED BY ALPHA-ZIRCONIUM PHOSPHATE AND ITS SODIUM AND POTASSIUM EXCHANGED FORMS [J].

CLEARFIELD, A ;

PACK, SP .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1975, 37 (05) :1283-1290

[8]

Clearfield A., 1982, INORGANIC ION EXCHAN

[9]

CLEARFIELD A, 1990, COMMENTS INORG CHEM, V10, P89

[10] ON THE EXISTENCE OF PYROPHOSPHATES OF TETRAVALENT METALS HAVING A LAYERED STRUCTURE [J].

COSTANTINO, U ;

LAGINESTRA, A .

THERMOCHIMICA ACTA, 1982, 58 (02) :179-189

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