SYNTHESIS AND MAGNETIC-PROPERTIES OF CU(II)-CO(II) AND CU(II)-MN(II) COMPLEXES WITH N,N'-ETHYLENEDISALICYLAMIDATOCUPRATE(II) AND 4,4'-DIMETHYL-2,2'-BIPYRIDYL

被引:16
|
作者
LIAO, DZ
JUAN, S
JIANG, ZH
YAN, SP
CHENG, P
WANG, GL
机构
[1] Department of Chemistry, Nankai University, Tianjin
基金
中国国家自然科学基金;
关键词
D O I
10.1016/S0277-5387(00)80231-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two heterobinuclear complexes have been synthesized, namely [Cu(samen) Co(Me2bpy)2] and [Cu(samen)Mn(Me2bPY)2], where samen and Me2bpy denote the N,N'-ethylenedisalicylamidate anion and 4,4'-dimethyl-2,2'-bipyridyl, respectively. The magnetic susceptibilities of the two complexes were measured in the range 4.2-300 K. The experimental data are treated in terms of three theoretical models and the results obtained are discussed.
引用
收藏
页码:2621 / 2624
页数:4
相关论文
共 50 条
  • [1] 2,2'-BIPYRIDYL AND 4,4'-BIPYRIDYL COMPLEXES WITH MN(II), CO(II), NI(II), CU(II), ZN(II) AND CD(II) ACETATES
    AHUJA, IS
    YADAVA, CL
    SINGH, R
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1981, 20 (11): : 1127 - 1130
  • [2] SYNTHESIS AND MAGNETIC-PROPERTIES OF CU(II)-MN(II) COMPLEXES WITH N,N'-BIS(2-AMINOETHYL)OXAMIDOCOPPER(II)
    MA, SL
    JIANG, ZH
    LIAO, DZ
    YAN, SP
    WANG, GL
    JOURNAL OF COORDINATION CHEMISTRY, 1994, 31 (04) : 321 - 327
  • [3] Synthesis and thermal behaviour of 4,4'-bipyridyl and 2,4'-bipyridyl complexes of Co(II), Ni(II) and Cu(II) thiocyanates
    CzakisSulikowska, D
    Kaluzna, J
    JOURNAL OF THERMAL ANALYSIS, 1996, 47 (06): : 1763 - 1776
  • [4] (4,4'-DIMETHYL-2,2'-BIPYRIDYL-N,N')BIS(ISOCYANATO)PLATINUM(II)
    COYER, MJ
    HERBER, RH
    COHEN, S
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 1376 - 1378
  • [5] Complexes of Mn(II), Co(II), Ni(II) and Cu(II) with 4,4'-bipyridine and dichloroacetates
    D. Czakis-Sulikowska
    A. Czylkowska
    Journal of Thermal Analysis and Calorimetry, 2003, 71 : 395 - 405
  • [6] Synthesis, crystal structure and thermal decomposition of Cu(II), Co(II), Mn(II) complexes with hetero-ligands containing cysteic acid, 4,4′-dimethyl-2,2′-bipyridine and azide
    Lehleh, Asma
    Beghidja, Adel
    Beghidja, Chahrazed
    Mentre, Olivier
    Welter, Richard
    COMPTES RENDUS CHIMIE, 2011, 14 (05) : 462 - 470
  • [7] Synthesis and Thermal Properties of 4,4'-bipyridine Adducts of Mn(II), Co(II), Ni(II) and Cu(II) Monochloroacetate
    D. Czakis-Sulikowska
    A. Czylkowska
    J. Radwańska-Doczekalska
    Journal of Thermal Analysis and Calorimetry, 2000, 63 : 387 - 395
  • [8] Synthesis and thermal properties of 4,4′-bipyridine adducts of Mn(II), Co(II), Ni(II) and Cu(II) monochloroacetate
    Czakis-Sulikowska, D
    Czylkowska, A
    Radwanska-Doczekalska, J
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2000, 63 (02) : 387 - 395
  • [9] SYNTHESIS AND MAGNETIC-PROPERTIES OF CU(II), NI(II) COMPLEXES BRIDGED BY 4,4'-BIPYRIDINE, PYRAZINE AND IMIDAZOLE
    LI, MX
    XU, Z
    YOU, XZ
    CHEN, CG
    CHEN, J
    ACTA CHIMICA SINICA, 1995, 53 (09) : 847 - 854
  • [10] Synthesis, Characterization and Antifungal Activity of Mn(II), Co(II), Ni(II) and Cu(II) Complexes with 4-Hydroxybenzaldehyde-N-4′ cytidinylazomethine
    Singh, Pratibha
    Kumar, Vikas
    Kumar, Manoj
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (04) : 1723 - 1727