CRYSTAL-STRUCTURE OF THE LOW-MELTING FORM OF FERROCENECARBOXALDOXIME

被引：5

作者：

FERGUSON, G ^{[1
]}

BELL, W ^{[1
]}

GLIDEWELL, C ^{[1
]}

机构：

[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 405卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0022-328X(91)86276-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An X-ray diffraction study shows that in the crystal of the low melting form of ferrocenecarboxaldoxime, (C5H5)Fe(C5H4CH = NOH) there are two molecular sites in the asymmetric unit, and both sites contain a disordered mixture of E and Z geometrical isomers. There are no close contacts between the iron atom and the hydroxyl group of the oxime substituent, but there is extensive intermolecular hydrogen bonding.

引用

页码：229 / 236

页数：8

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