ANALOGS OF URIDINE 5'-DIPHOSPHATE GLUCOSE AND GUANOSINE 5'-DIPHOSPHATE MANNOSE

被引：0
作者：
BROXTERMAN, HJG
KOOREMAN, PA
VANDENELST, H
ROELEN, HCPF
VANDERMAREL, GA
VANBOOM, JH
机构：
来源：
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY | 1990年 / 109卷 / 12期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One-pot coupling of 2',3'-di-O-benzoyl-uridine and 4,5,6,8-tetra-O-acetyl-3,7-anhydro-2-deoxy-D-glycero-D-ido-octitol with appropriate bifunctional phosphoro-, phosphono- and thiophosphonylation reagents gave, after removal of the base-labile protecting groups, analogues of UDP-Glc containing charged phosphate, neutral alkyl- and arylphosphonate and phosphonothioate linkages. In an analogous manner, GDP-Man analogues, in which guanosine and octitol units are similarly linked via phosphate, alkyl phosphate or phosphotriester bonds, were prepared.
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页码：583 / 590
页数：8
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