ANALOGS OF URIDINE 5'-DIPHOSPHATE GLUCOSE AND GUANOSINE 5'-DIPHOSPHATE MANNOSE

被引：0

作者：

BROXTERMAN, HJG

KOOREMAN, PA

VANDENELST, H

ROELEN, HCPF

VANDERMAREL, GA

VANBOOM, JH

机构：

来源：

RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY | 1990年 / 109卷 / 12期

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D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-pot coupling of 2',3'-di-O-benzoyl-uridine and 4,5,6,8-tetra-O-acetyl-3,7-anhydro-2-deoxy-D-glycero-D-ido-octitol with appropriate bifunctional phosphoro-, phosphono- and thiophosphonylation reagents gave, after removal of the base-labile protecting groups, analogues of UDP-Glc containing charged phosphate, neutral alkyl- and arylphosphonate and phosphonothioate linkages. In an analogous manner, GDP-Man analogues, in which guanosine and octitol units are similarly linked via phosphate, alkyl phosphate or phosphotriester bonds, were prepared.

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页码：583 / 590

页数：8

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