INFRARED-ABSORPTION COEFFICIENTS OF SILICA GLASSES

The absorption coefficient values of several silicate glasses in the IR radiation range were determined. Four methods were employed in this study: (1) direct transmission by CO2 laser, (2) direct transmission through ultrathin sections using an IR spectrometer, (3) glass particle dispersions in KBr pressed pellets, and (4) IR reflection spectral analysis. Wide variations in values were observed for some of these techniques. The reasons for the variations were explored, and evidence is presented to support the conclusion that the reflection measurements and the low-power transmission technique yield accurate values. The pellet technique was found to possess too many experimental variables which could not be controlled and gave erroneous data. The damage produced by direct transmission of high-power radiation was severe and introduced effects which gave spurious results.