MOLECULAR-LIKE BEHAVIOR AND VECTOR CORRELATIONS FOR THE MG+FH REACTION

被引：9

作者：

ALVARINO, JM ^{[1
]}

LAGANA, A ^{[1
]}

机构：

[1] UNIV PERUGIA,DIPARTIMENTO CHIM,I-06100 PERUGIA,ITALY

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 09期

关键词：

D O I：

10.1021/j100188a008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The presence of an insertion well in the potential energy surface of alkaline earth metal hydrogen halide systems has interesting effects on the vector properties of the reaction products. In this paper, we discuss the effect of forming a short-lived insertion complex on the alignment of the product diatomic rotational angular momentum to the products' relative velocity vector for the Mg + FH reaction. Similarities with correlation properties of photodissociating triatomic molecules and the effect of increasing the total angular momentum are examined.

引用

页码：3587 / 3590

页数：4

共 19 条

[1] COMPETING MECHANISMS AND PRODUCTS PROPERTIES FOR THE BE+HF REACTION [J].