Anomalous rotation-vibration coupling in molecule

被引:0
|
作者
Konarski, J
机构
来源
BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY | 1995年 / 43卷 / 04期
关键词
rotation-vibrational coupling; rotation constant; centrifugal distorsion constant; rovibrational energy;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It was shown that there are some molecules for which the weak coupling between vibrational and rotational motions does not take place, and these molecules reveal the anomalous rotation-vibration coupling. The rigid body model cannot describe their properties accurately. There is necessity of a more sophisticated approach, based on the deformable body model.
引用
收藏
页码:279 / 285
页数:7
相关论文
共 50 条