SYNTHESIS OF NEW POLYMERS CONTAINING ALPHA-(TRIFLUOROMETHYL)ACRYLATE UNITS

被引：32
作者：
AGLIETTO, M
PASSAGLIA, E
DIMIRABELLO, LM
BOTTEGHI, C
PAGANELLI, S
MATTEOLI, U
MENCHI, G
机构：
[1] UNIV VENICE,DIPARTIMENTO CHIM,I-30100 VENICE,ITALY
[2] UNIV FLORENCE,DIPARTIMENTO CHIM ORGAN,I-50121 FLORENCE,ITALY
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 1995年 / 196卷 / 09期
关键词：
D O I：
10.1002/macp.1995.021960910
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Free radical polymerization of both alpha-(trifluoromethyl)acrylic acid (TFMAA) and its methyl ester MTFMA is shown to be possible in the presence of bis(4-tert-butylcyclohexyl) peroxycarbonate (Percadox) as initiator and dioxane or THF as solvent. Also it is shown that copolymers of TFMAA with alpha-olefins (1-decene, 2-methyl-1-hexene) and of methyl alpha-(trifluoromethyl)acrylate (MTFMA) with vinyl ethers (butyl, 2-ethylhexyl, and menthyl vinyl ether) can be simply obtained with AIBN as initiator; these copolymers have a predominantly alternating structure.
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页码：2843 / 2853
页数：11
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