A NEW OLEFIN SYNTHESIS BASED ON THE RADICAL-INDUCED ELIMINATION OF A NITRO-GROUP

被引：6
作者：
BARTON, DHR
DORCHAK, J
JASZBERENYI, JC
机构：
[1] Department of Chemistry, Texas A and M University, College Station
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 50期
关键词：
D O I：
10.1016/S0040-4039(00)61448-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Nitroalkanes can be transformed into olefins in high yielding reactions via nitroolefins and beta-nitro trithiocarbonates in radical olefination reactions.
引用
收藏
页码：8051 / 8054
页数：4
相关论文
共 37 条
[1]  
Baer H H, 1969, Adv Carbohydr Chem Biochem, V24, P67
[2]   CHEMOSELECTIVE SYNTHESIS OF FUNCTIONALIZED CONJUGATED NITROALKENES [J].
BALLINI, R ;
CASTAGNANI, R ;
PETRINI, M .
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (07) :2160-2162
[3]   CONJUGATED NITROALKENES - VERSATILE INTERMEDIATES IN ORGANIC-SYNTHESIS [J].
BARRETT, AGM ;
GRABOSKI, GG .
CHEMICAL REVIEWS, 1986, 86 (05) :751-762
[4]   ON THE MECHANISM OF DEOXYGENATION OF SECONDARY ALCOHOLS BY TIN HYDRIDE REDUCTION OF METHYL XANTHATES AND OTHER THIOCARBONYL DERIVATIVES [J].
BARTON, DHR ;
JANG, DO ;
JASZBERENYI, JC .
TETRAHEDRON LETTERS, 1990, 31 (28) :3991-3994
[5]   PHOTOLYTIC GENERATION OF CARBON RADICALS FROM BARTON ESTERS - RECENT DEVELOPMENTS [J].
BARTON, DHR ;
JASZBERENYI, JC ;
TANG, DG .
TETRAHEDRON LETTERS, 1993, 34 (21) :3381-3384
[6]   THE INVENTION OF RADICAL REACTIONS .21. SIMPLE METHODS FOR THE RADICAL DEOXYGENATION OF PRIMARY ALCOHOLS [J].
BARTON, DHR ;
BLUNDELL, P ;
DORCHAK, J ;
JANG, DO ;
JASZBERENYI, JC .
TETRAHEDRON, 1991, 47 (43) :8969-8984
[7]   A MILD PROCEDURE FOR THE REDUCTION OF ALIPHATIC NITROCOMPOUNDS TO OXIMES [J].
BARTON, DHR ;
FERNANDEZ, I ;
RICHARD, CS ;
ZARD, SZ .
TETRAHEDRON, 1987, 43 (03) :551-558
[8]   THE INVENTION OF CHEMICAL-REACTIONS - THE LAST 5 YEARS [J].
BARTON, DHR .
TETRAHEDRON, 1992, 48 (13) :2529-2544
[9]   THE INVENTION OF RADICAL REACTIONS .24. RELATIVE RATES OF ACYLATION AND RADICAL DEOXYGENATION OF SECONDARY ALCOHOLS [J].
BARTON, DHR ;
DORCHAK, J ;
JASZBERENYI, JC .
TETRAHEDRON, 1992, 48 (36) :7435-7446
[10]   NEW METHOD FOR DEOXYGENATION OF SECONDARY ALCOHOLS [J].
BARTON, DHR ;
MCCOMBIE, SW .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (16) :1574-1585
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